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Catalytic hydrogenation of carbon monoxide and dioxide over steel

 

作者: Buford D. Smith,   Robert R. White,  

 

期刊: AIChE Journal  (WILEY Available online 1956)
卷期: Volume 2, issue 1  

页码: 46-54

 

ISSN:0001-1541

 

年代: 1956

 

DOI:10.1002/aic.690020110

 

出版商: American Institute of Chemical Engineers

 

数据来源: WILEY

 

摘要:

AbstractThe hydrogenation of carbon monoxide and carbon dioxide on various steel catalysts was studied in the temperature range of 800° to 1,300°F. and at pressures from 5 to 30 atm. The feed gases (3.75 to 20 SCFH) were passed over a catalyst bed of 1/8‐in. steel balls supported in a brass‐lined reactor 0.81 in. in diam. The percentage of carbon oxides in the feed was 30% in the runs using a H2CO2feed and varied from 15 to 38% in the runs with a H2CO feed. The effects of temperature, pressure, feed composition, space velocity, and mass velocity were studied. Carbon deposition did not affect the activity of the catalyst and could be remove

 

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