Improved synthesis of 5(6)‐vinylbenzimidazole: Some polymerization studies
作者:
C. G. Overberger,
L. J. Mathias,
期刊:
Journal of Polymer Science: Polymer Chemistry Edition
(WILEY Available online 1978)
卷期:
Volume 16,
issue 3
页码: 627-631
ISSN:0360-6376
年代: 1978
DOI:10.1002/pol.1978.170160307
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractA general one‐step reduction ring closure ofo‐nitroacetanalides is applied to the synthesis of 5(6)‐acetylbenzimidazole and 5(6)‐acetyl‐2‐methylbenzimidazole in good yield. The former is readily converted to the vinyl monomer by reduction and dehydration. Polymerization of this monomer with free‐radical initiation under a variety of conditions gives polymers with essentially identical nuclear magnetic resonance (NMR) spectra, implying no basic change in poly
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