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Generation of free radicals by increasing the temperature after γ-irradiation of polyethylene

 

作者: Peter Wünsche,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1984)
卷期: Volume 23, issue 1  

页码: 65-84

 

ISSN:0022-2348

 

年代: 1984

 

DOI:10.1080/00222348408229362

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The total radical decay in γ-irradiated polyethylene, measured by EPR, is discussed. By using the model of broad distribution of reaction constants and by an improvement of the estimate of radical concentrations, it is proved that radical-generating reactions occur during the temperature increase after γ-irradiation. The number of total radicals produced that are generated during the temperature increase is of the same order of magnitude as the radicals initially produced by the γ-irradiation. Some arguments are summarized to support the applicability of the model of broad distribution.

 

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