Generation of free radicals by increasing the temperature after γ-irradiation of polyethylene
作者:
Peter Wünsche,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1984)
卷期:
Volume 23,
issue 1
页码: 65-84
ISSN:0022-2348
年代: 1984
DOI:10.1080/00222348408229362
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The total radical decay in γ-irradiated polyethylene, measured by EPR, is discussed. By using the model of broad distribution of reaction constants and by an improvement of the estimate of radical concentrations, it is proved that radical-generating reactions occur during the temperature increase after γ-irradiation. The number of total radicals produced that are generated during the temperature increase is of the same order of magnitude as the radicals initially produced by the γ-irradiation. Some arguments are summarized to support the applicability of the model of broad distribution.
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