Synthesis, Structure and Optical Properties of Cupro‐8‐thioquinoline Coordination Polymer, [CuI(C9H6NS)]n
作者:
Zhang Guo‐Hong,
Wang Ping,
Guo Hong‐You,
Wu Nian‐Zu,
Jin Xiang‐Lin,
期刊:
Chinese Journal of Chemistry
(WILEY Available online 2003)
卷期:
Volume 21,
issue 1
页码: 40-43
ISSN:1001-604X
年代: 2003
DOI:10.1002/cjoc.20030210111
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: coordination polymer;cupro‐8‐thioquinoline complex;synthesis;crystal structure
数据来源: WILEY
摘要:
AbstractA Cupro‐8‐thioqinoline coordination polymer, [CuI(C9H6NS)]n, was synthesized by methano‐thermal reaction of CuCl and 8,8′‐dithiodiquinoline (dtdq) in a molar ratio of 2:1 at 160°C for 7 d. X‐Ray single crystal structure determination revealed the formation of a one‐dimensional structure belonging to monoclinic crystal system, space groupP21/cwith cell parametersa= 0.8043(1) nm,b= 1.8949(3) nm,c= 1.1048(1) nm, β = 110.109(4)°,V= 1.5810(4) nm3andZ= 4. The crystal was found to be stable up to approximately 300°C by thermal analysis and have an energy gap (Eg) of 2.0 eV exhibited by UV‐Vis‐NIR
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