Polyhalovinyl Sulfones as Polyfunctional Electrophilic Substrates in Reactions with Nucleophiles
作者:
BagratA. Shainyan,
期刊:
Sulfur reports
(Taylor Available online 1995)
卷期:
Volume 16,
issue 2
页码: 223-232
ISSN:0196-1772
年代: 1995
DOI:10.1080/01961779508048739
出版商: Taylor & Francis Group
关键词: Polyhalovinyl sulfones;nucleophilic vinylic substitution;halophilic reduction;rearrangements
数据来源: Taylor
摘要:
In the present review the results of investigations of the chemical properties of polyhalovinyl sulfones are summarized. The main accent is made on their ability to react with nucleophiles at different electrophilic sites depending on the nature and the number of halogen substituents as well as on the nucleophile. Special attention is given to the halophilic reduction of these electrophiles by soft nucleophiles. The synthetic potential of polyhalovinyl sulfones as synthons for various heterocycles in reactions with polydentate S- and N-nucleophiles is also demonstrated.
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