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Infrared Spectroscopy in Electrochemistry: New Methods and Connections to UhV Surface Science

 

作者: Carol Korzeniewski,  

 

期刊: Critical Reviews in Analytical Chemistry  （Taylor Available online 1997）
卷期: Volume 27, issue 2  

页码: 81-102

 

ISSN:1040-8347

 

年代: 1997

 

DOI:10.1080/10408349708050584

 

出版商: Taylor & Francis Group

 

关键词: infrared spectroscopy;electrochemistry;surface chemistry;single crystal electrodes;vibrational coupling.

 

数据来源: Taylor

 

摘要:

This review discusses recent advances in the use of infrared spectroscopy in electrochemistry. The central focus is on analytical factors that affect the ability to derive structural information from infrared spectra of molecular adlayers. The effects of vibrational coupling and dielectric screening are emphasized. Applications of real-time polarization modulation and step-scan Fourier transform infrared spectroscopy are also presented.

 

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