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A constitutive analysis of extensional flows of polyisobutylene

 

作者: M. H. Wagner,   A. Demarmels,  

 

期刊: Journal of Rheology  (AIP Available online 1990)
卷期: Volume 34, issue 6  

页码: 943-958

 

ISSN:0148-6055

 

年代: 1990

 

DOI:10.1122/1.550107

 

出版商: The Society of Rheology

 

关键词: Integral viscoelastic constitutive equation;Polyisobutylene melt;Extensional flow;First normal stress difference;Second normal stress difference;ORGANIC POLYMERS;2−METHYLPROPENE;MELTS;STRAINS;RHEOLOGY;VISCOELASTICITY

 

数据来源: AIP

 

摘要:

By analyzing uniaxial, planar, ellipsoidal, and equibiaxial extension data, a viscoelastic constitutive equation of the single integral form is derived for a polyisobutylene (PIB) melt. Within experimental limits, time and strain effects are separable. The strain dependence corresponds to a Mooney‐type combination of Finger and Cauchy tensors, modified by a damping functionh(I1,I2), which depends on the strain invariantsI1andI2of the Finger tensor. It is shown that the ratio of the second to the first normal stress difference in shear flow β can be extracted from planar extension experiments. For the PIB melt considered, β turns out to be negative and equal to β=−0.27, and to be independent of strain. The influence of β on the tensions in general extensional flow is discussed.

 

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