PERMEATION THROUGH KAPTON® POLYIMIDE AT ELEVATED TEMPERATURES
作者:
M. HAUSLADEN,
K. A. LASALA,
C. R. F. LUND,
期刊:
Chemical Engineering Communications
(Taylor Available online 1996)
卷期:
Volume 143,
issue 1
页码: 91-97
ISSN:0098-6445
年代: 1996
DOI:10.1080/00986449608936435
出版商: Taylor & Francis Group
关键词: Permeation;Polyimide;Methane;Methanol
数据来源: Taylor
摘要:
The permeabilities of CH4, CO2, CH3OH, H2O, O2, and CO through films of Kapton® polyimide were measured at temperatures of 50, 100, 150, 200, and 250°C and pressures below 1 atm. Apparent activation energies for the permeation of the pure components ranged from 31.6kJ mol−1for CH4to nearly 0 for H2O under the conditions studied. The ideal permselectivity for methanol relative to methane decreased from over 100 to under 10 as the temperature was increased from 50 to 250°C.
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