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Heterophane mit 1,3,5‐Triazinbausteinen und Thiol/Disulfid‐Redoxschalter

 

作者: H. Graubaum,   F. Tittelbach,   G. Lutze,   K. Gloe,   M. Mackrodt,  

 

期刊: Journal für Praktische Chemie/Chemiker‐Zeitung  （WILEY Available online 1997）
卷期: Volume 339, issue 1  

页码: 55-58

 

ISSN:0941-1216

 

年代: 1997

 

DOI:10.1002/prac.19973390108

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Heterophanes with 1,3,5‐Triazines as Subunits and Thiol/Disulfide Redox SwitchThe synthesis and characterization of 5 new coronands2a–e, containing two 1,3,5‐triazine‐thiols as subunits and redox‐switch are described. Cryptands3a–ewith disulfide bridges were obtained by oxidation. Reduction of cryptands3a–eyields back the coronands2a–e. The different complexation properties of the macrocycles2a–dand3a–dtoward Tl(I), Ag(I) and Hg(II

 

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