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Rheo‐optical studies on aligned nematic solutions of a rodlike polymer

 

作者: Mohan Srinivasarao,   G. C. Berry,  

 

期刊: Journal of Rheology  (AIP Available online 1991)
卷期: Volume 35, issue 3  

页码: 379-397

 

ISSN:0148-6055

 

年代: 1991

 

DOI:10.1122/1.550220

 

出版商: The Society of Rheology

 

关键词: Polymeric liquid crystals;Rodlike polymer dynamics;Director orientations;Tumbling flaws;Leslie–Ericksen equations;SHEAR FLOW;NEMATIC CRYSTALS;BENZOTHIAZOLES;PHENYLENE RADICALS;ORGANIC POLYMERS;SOLUTIONS

 

数据来源: AIP

 

摘要:

Rheo‐optical studies on shear deformation of well‐aligned nematic solutions of the rodlike poly (1,4‐phenylene‐2,6‐benzobisthiazole), PBT, are reported. Conoscopic microscopy was used to follow the director during shear, and during relaxation on cessation of flow. The results show that the molecules are not homogeneously aligned in shearing flow. Rather, various complex director field distortions may occur, depending on the relative orientation of the initial director to the flow direction. The results are compared quantitatively with predictions based on the Ericksen–Leslie constitutive equation for nematic fluids.

 

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