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Cationic Phosphine‐imine ρodium(I) Complexes and Their Activity on Catalysis of Phenylacetylene Polymerization

 

作者: K. Rajender Reddy,   Chi‐Feng Lin,   Gene‐Hsiang Lee,   Shie‐Ming Peng,   Jwu‐Ting Chen,   Shiuh‐Tzung Liu,  

 

期刊: Journal of the Chinese Chemical Society  （WILEY Available online 2001）
卷期: Volume 48, issue 6A  

页码: 997-1002

 

ISSN:0009-4536

 

年代: 2001

 

DOI:10.1002/jccs.200100146

 

出版商: WILEY‐VCH Verlag

 

关键词: Rhodium;Polymerization;Phenylacetylene;Alkyne;Aqueous medium

 

数据来源: WILEY

 

摘要:

AbstractA series of phosphine‐imine rhodium(I) complexes have been prepared and characterized by both spectroscopic and X‐ray single crystal analyses. Their activity on catalytic polymerization of phenylacetylene is investigated. The study of the solvent effect on polymerization shows that aqueous medium can in crease the productivity of poly

 

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