Styrene polymerization induced by anilino radicals
作者:
Kazuo Sugiyama,
Tetsuo Oda,
Toshihisa Maeshima,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 1
页码: 1-8
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830101
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe polymerization of styrene (St) initiated by 1,4‐dimethyl‐1,4‐diphenyl‐2‐tetrazene (1c) is studied kinetically in benzene. The polymerization proceeds through a radical mechanism. The rate equation is as follows:Rp=k[1c]0,5[St]1,0. The overall activation energy for the polymerization of St is found to be 105,9 kJ · mol−1. The efficiency of the initiator is also calculated to be 0,67. On the basis of the results, the initiating ability ofN‐methylanilino radical
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