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Synthetic morphinans and hasubanans. VI. Total synthesis of 3-hydroxyisomorphinans, 3-hydroxyhasubanans, and 3,9-dihydroxyhasubanans

 

作者: Ivo Monković,   Henry Wong,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1976）
卷期: Volume 54, issue 6  

页码: 883-891

 

ISSN:0008-4042

 

年代: 1976

 

DOI:10.1139/v76-128

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

A new total synthesis of racemic 3-hydroxyisomorphinans (3), 3-hydroxyhasubanans (9), 3,9α-dihydroxyhasubanans (5), and 3,9β-dihydroxyhasubanans (7), via 4a-(2-aminoethyl)-1,2,3,4,4a,9-hexahydro-6-methoxyphenanthrene (1a) is described.

 

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