Kinetic Models for Hydrogen Peroxide Bleaching of Mechanical Pulps
作者:
Steve Moldenius,
Birger Sjögren,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1982)
卷期:
Volume 2,
issue 4
页码: 447-471
ISSN:0277-3813
年代: 1982
DOI:10.1080/02773818208085145
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Several commercial thermomechanical pulps and stone ground-wood pulps were bleached to determine how the bleaching rate is affected by peroxide and alkali concentration, pulp consistency and temperature. The bleaching rate seems to be determined by the balance between the bleaching action of peroxide anion (HO) and color formation by alkali (OH). At a given peroxide concentration, increased alkalinity increased the bleaching rate due to the formation of peroxide anion, up to a given alkali concentration above which a further increase led to a decrease in reaction rate. This is probably due to the fact that at high alkalinity, pOH < 2.5, an increase in hydroxide ion concentration gives only a slight increase in the peroxide anion concentration, at lower alkalinity, the increase in peroxide anion concentration is approximately proportional to that of the hydroxide ion.
点击下载:
PDF (656KB)
返 回