IONIC SPECIES OF TETRAVALENT URANIUM IN PERCHLORIC AND SULPHURIC ACIDS
作者:
R. H. Betts,
Rita M. Leigh,
期刊:
Canadian Journal of Research
(NRC Available online 1950)
卷期:
Volume 28b,
issue 8
页码: 514-525
ISSN:1923-4287
年代: 1950
DOI:10.1139/cjr50b-062
出版商: NRC Research Press
数据来源: NRC
摘要:
A quantitative study of the extraction of tetravalent uranium into benzene by the action of the organic chelating agent thiophenoyl trifluoracetone is described. Data are presented to show that the uranous ion exists mainly in the quadruply charged form in solutions of perchloric acid. It is extracted into benzene as a neutral molecule containing four chelate groups per metal atom. At least two complex species, U(SO4)++and U(SO4)2are present in sulphuric acid solutions. Values of the association constants for the formation of these complex species are given.
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