Nuclear Magnetic Resonance Studies of Molecular Motion in Some Elastomers
作者:
W. P. Slichter,
D. D. Davis,
期刊:
Journal of Applied Physics
(AIP Available online 1964)
卷期:
Volume 35,
issue 11
页码: 3103-3108
ISSN:0021-8979
年代: 1964
DOI:10.1063/1.1713187
出版商: AIP
数据来源: AIP
摘要:
The nuclear magnetic resonance (NMR) relaxation has been studied in polyisobutylene and polybutadiene at temperatures from −170° to +200°C and at three resonance frequencies: 20, 30, and 50 Mc/sec. In polyisobutylene, the spin‐lattice relaxation time (T1) passes through two minima with change in temperature. The low‐temperature minimum is ascribed, as in other compounds, to methyl‐group rotation, but in polyisobutylene this motion is found to encounter relatively large hindrance, presumably owing to inter‐locking among the groups. The high‐temperatureT1‐minimum is ascribed to rotational and translational motion of the segments. The extent of motion is qualitatively gauged by calculation from the Bloembergen‐Purcell‐Pound theory for NMR relaxation in simple liquids.T1is insensitive to molecular weight (M.W.) over a wide range, but the dependence ofT2upon M.W. changes abruptly when M.W.≅4×104. In polybutadiene,T1is found to depend markedly on thecis‐transcontent.
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