Rearrangement reactions of phenyl chloroformate derivatives of 2‐Hydroxyaminoacetanilides to hydantoins, ureas and hydantoie acid derivatives
作者:
Stanley C. Hell,
George Conklin,
Ronald J. Mccaully,
期刊:
Journal of Heterocyclic Chemistry
(WILEY Available online 1976)
卷期:
Volume 13,
issue 1
页码: 51-55
ISSN:0022-152X
年代: 1976
DOI:10.1002/jhet.5570130109
出版商: Wiley‐Blackwell
数据来源: WILEY
摘要:
AbstractAlkaline treatment of 2′‐benzoyl‐2‐(N‐carbophenoxy‐N‐hydroxyamino)‐4′‐chloroacetanilide (10) and its corresponding acetate6afforded respectively 5‐(2‐benzoyl‐4‐chlorophenyl)‐3‐hydroxy‐hydantoic acid (12) and 6‐chloro‐4‐phenylquinazolone (13). A study of the course of the reaction was carried out with the corresponding compounds that are devoid of the 2‐benzoyl group. An elucidation of the rearrangement is based on the isolation and independent sy
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