Δ1‐pyrazolines: (Pyrazol and pyrazoline derivatives II
作者:
J. van Alphen,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1943)
卷期:
Volume 62,
issue 5
页码: 334-336
ISSN:0165-0513
年代: 1943
DOI:10.1002/recl.19430620506
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractΔ1‐pyrazolines, in which the double bond is situated between the two nitrogen atoms can be prepared by the addition of diphenyldiazomethane to the diphenyl ester of citraconic acid and to the trimethyl ester of aconitic acid. These compounds split off nitrogen at higher temperatures forming cyclopropane derivatives.Diphenyl diazomethane combines directly with citraconic acid anhydride, splitting off nitrog
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