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Regioselective deuterium labelling of aromatic acids, amides and amines using group VIII metal catalysts

 

作者: W J S Lockley,  

 

期刊: Journal of Labelled Compounds and Radiopharmaceuticals  （WILEY Available online 1984）
卷期: Volume 21, issue 1  

页码: 45-57

 

ISSN:0362-4803

 

年代: 1984

 

DOI:10.1002/jlcr.2580210105

 

出版商: John Wiley&Sons, Ltd.

 

关键词: Ortho‐deuteration;[2,6‐2H2]Benzoic acid;[3,4,5‐2H3] Benzoic acid;Rhodium trichloride;[2,6‐2H2]Benzamide;[2,6‐2H2]Benzylamine

 

数据来源: WILEY

 

摘要:

AbstractOrtho‐deuterated arylcarboxylic acids and their sodium salts may be prepared with high regioselectivity by isotopic exchange with deuterium oxide in the presence of a range of commercially available group VIII metal complexes. When rhodium trichloride trihydrate is employed a range of arylcarboxamides and arylmethanamines are also selectively labelled at theortho‐positi

 

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