首页   按字顺浏览 期刊浏览 卷期浏览 A model for the Magill‐Li viscosity‐temperature relation
A model for the Magill‐Li viscosity‐temperature relation

 

作者: S. M. Breitling,   J. H. Magill,  

 

期刊: Journal of Applied Physics  (AIP Available online 1974)
卷期: Volume 45, issue 10  

页码: 4167-4171

 

ISSN:0021-8979

 

年代: 1974

 

DOI:10.1063/1.1663032

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A simple model has been developed to account for the viscosity‐temperature dependence of liquids. It is predicated upon the valid assumption that the activation energy for flow is Arrhenius‐like at sufficiently high temperatures, and that this activation energy varies inversely as the probability of finding sufficient local volume for transport at lower temperatures. The model yields a viscosity reducing equation very similar to the Magill‐Li empirical equation for the zero shear viscosity &eegr; as the function of temperatureT. The relation isln&eegr;&eegr;s=Aexp [B (x+&phgr;−1)−1]x−exp(B/2 &phgr;)1+&phgr;,whereA= 2.68,B= 0.432, &phgr; = 0.238,x=T/Tg, &eegr;Sis the reference viscosity at the reference temperatureTs, andTgis the glass temperature. This relation has been successful in reducing data for several viscous materials unto a single master curve which extends over about 16 orders of magnitude in viscosity and encompasses a broad temperature range extending fromTgto about 2.5Tgin some instances.

 

点击下载:  PDF (298KB)



返 回