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“Active monomer” polymerization of δ‐benzylL‐α‐aminoadipate

 

作者: Nam S. Choi,   Murray Goodman,  

 

期刊: Biopolymers  （WILEY Available online 1972）
卷期: Volume 11, issue 1  

页码: 67-78

 

ISSN:0006-3525

 

年代: 1972

 

DOI:10.1002/bip.1972.360110105

 

出版商: Wiley Subscription Services, Inc., A Wiley Company

 

数据来源: WILEY

 

摘要:

AbstractTheN‐carboxyanhydride of δ‐benzylL‐α‐aminoadipate polymerizes when initiated by strong base through an “active monomer” mechanism. This is shown by the isolation of 6‐oxo‐L‐pipecolic acid from the product mixture, since this byproduct could only arise from an “active monomer” pathway. This study also specifies conditions for preparing high molecular weight poly(δ‐benzylL‐

 

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