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1,2‐Bis(o‐aminophenoxy)ethane‐N,N,N′,N′‐tetra‐acetic acid derivatives on complexation with lanthanoid metal ions. Correlation between size of trapping hole and metal ion

 

作者: Takahide Kimura,   Takashi Ando,   Tetsushi Maruyama,   Takashi Sugiyama,   Atsuyoshi Ohno,   Mutsuo Okamura,  

 

期刊: Heteroatom Chemistry  (WILEY Available online 1995)
卷期: Volume 6, issue 1  

页码: 57-62

 

ISSN:1042-7163

 

年代: 1995

 

DOI:10.1002/hc.520060113

 

出版商: VCH Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractComplexation of lanthanoid metal ions with 1,2‐bis(o‐aminophenoxy)‐ethane‐N,N,N′,N′‐tetraacetic acid and its two derivatives, in which the distance between the chelating functions is changed, has been studied by potentiometric pH titration. There are two complexation modes depending on the size of the metal ion. Structural flexibility of the chelator accounts for the change in the comp

 

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