Ternary Complexes in Solution: Mixed Ligand Complexes of Co(lI), Ni(ll), Zn(lI), or Cd(lI) with N, S Donor Ligands
作者:
R.S. Thakur,
C.S. Bhandari,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 16,
issue 3
页码: 729-736
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108056819
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The stability constants of ternary Co(II), Ni(II), Zn(II), or Cd(II) complexes containing 2,2′-bipyridyl (bipy) or 1,10-phenanthroline (phen) as a primary ligand and N-phenyl-2-mercaptopropion-amide (PMP) as a secondary ligand in a 1:1:1 molar ratio were determined using the Irving-Rossotti pH-titration technique in a 70% (v/v) dioxane-water mixture (I=0.1 M NaC104; 30 ± 1°C) in an inert atmosphere. The stability of these ternary complexes is discussed on the basis of π -accepting qualities of the sulfur ligand and the participating heteroaromatic N-base.
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