β-Cyclodextrin Effect on Micellization of Cetyltrimethyl ammonium Bromide in Aqueous Solution. Probed by Dual Fluorescence of Sodium P-Dimethylaminobenzoate
作者:
Li-Rong Lin,
Yun-Bao Jiang,
Xian-Zhi Huang,
Guo-Zhen Chen,
期刊:
Spectroscopy Letters
(Taylor Available online 1997)
卷期:
Volume 30,
issue 8
页码: 1551-1560
ISSN:0038-7010
年代: 1997
DOI:10.1080/00387019708006743
出版商: Taylor & Francis Group
关键词: P-cyclodextrin;Micellization;Cetyltrimethylammouium bromide;Twisted intramolecular charge Transfer(TICT);Sodium p-dimethylaminobenzoate
数据来源: Taylor
摘要:
Effect of p-cyclodextrin (β-CD) on micellization of cetyltrimethylammonium bromide (CTAB) in aqueous solution was investigated by twisted intramolecular charge transfer (TICT) dual fluorescence of sodium p-dimethylaminobenzoate (SDMAB). It was shown that β-CD induces the micellization of CTAB and the aggregation of CTAB below CMC as well. A reduced charge density at CTAB micelle interface in the presence of β-CD, due to the incorporation of 1:1 CTAB-β-CD inclusion complex in micelle, was concluded to be the reason for β-CD induced micellization of CTAB.
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