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β-Cyclodextrin Effect on Micellization of Cetyltrimethyl ammonium Bromide in Aqueous Solution. Probed by Dual Fluorescence of Sodium P-Dimethylaminobenzoate

 

作者: Li-Rong Lin,   Yun-Bao Jiang,   Xian-Zhi Huang,   Guo-Zhen Chen,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1997)
卷期: Volume 30, issue 8  

页码: 1551-1560

 

ISSN:0038-7010

 

年代: 1997

 

DOI:10.1080/00387019708006743

 

出版商: Taylor & Francis Group

 

关键词: P-cyclodextrin;Micellization;Cetyltrimethylammouium bromide;Twisted intramolecular charge Transfer(TICT);Sodium p-dimethylaminobenzoate

 

数据来源: Taylor

 

摘要:

Effect of p-cyclodextrin (β-CD) on micellization of cetyltrimethylammonium bromide (CTAB) in aqueous solution was investigated by twisted intramolecular charge transfer (TICT) dual fluorescence of sodium p-dimethylaminobenzoate (SDMAB). It was shown that β-CD induces the micellization of CTAB and the aggregation of CTAB below CMC as well. A reduced charge density at CTAB micelle interface in the presence of β-CD, due to the incorporation of 1:1 CTAB-β-CD inclusion complex in micelle, was concluded to be the reason for β-CD induced micellization of CTAB.

 

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