Quasiliving Carbocationic Polymerization. X. Molecular Weight Averages and Polydispersity
作者:
Tibor Kelen,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 9
页码: 1339-1351
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208077227
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In quasiliving polymerizations with reversible chain transfer (QL0Rsystems), polymers with narrow molecular weight distribution can be obtained, It has been shown that while in true living systems (L00) R = 1, and in quasiliving systems with irreversible chain transfer (QL01) R = 2 is the limiting value of polydispersity, in QL0Rsystems r = 4/3 is the polydispersity to which the distribution of the polymer tends with increasing polymerization time. This limit is independent of the rate of reinitiation; the course of the R vs t curves is, however, determined by the various rate constants.
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