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Quasiliving Carbocationic Polymerization. X. Molecular Weight Averages and Polydispersity

 

作者: Tibor Kelen,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1982)
卷期: Volume 18, issue 9  

页码: 1339-1351

 

ISSN:0022-233X

 

年代: 1982

 

DOI:10.1080/00222338208077227

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In quasiliving polymerizations with reversible chain transfer (QL0Rsystems), polymers with narrow molecular weight distribution can be obtained, It has been shown that while in true living systems (L00) R = 1, and in quasiliving systems with irreversible chain transfer (QL01) R = 2 is the limiting value of polydispersity, in QL0Rsystems r = 4/3 is the polydispersity to which the distribution of the polymer tends with increasing polymerization time. This limit is independent of the rate of reinitiation; the course of the R vs t curves is, however, determined by the various rate constants.

 

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