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Correlated diffusion-controlled kinetics

 

作者: D. Peak,   H.L. Frisch,   J.W. Corbett,  

 

期刊: Radiation Effects  (Taylor Available online 1971)
卷期: Volume 11, issue 3-4  

页码: 149-154

 

ISSN:0033-7579

 

年代: 1971

 

DOI:10.1080/00337577108231100

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The theory of diffusion-limited bimolecular reaction kinetics is investigated for the case in which the reactants are initially produced in spatially correlated pairs. The intent of the study is to discover to what extent information concerning the initial distribution of pair member separations (generally unknown for such systems) can be deduced from empirically observable quantities. The analysis predicts the form of the dependence of the fractional concentration of recombined pairs on various moments of the distribution function as well as the approximate concentration dependence of very late time correlated reactions. It is expected that the model may be applicable to many systems of radiation-and photo-physics, chemistry, and biology; the specific examples of radical reactions in solution and the annealing of damage produced by electron irradiation of metals and semiconductors are discussed.

 

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