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Measurement of Association Constants in Metal Orotate Complexes by1H NMR Spectroscopy: the Metal Substituent Effect on Triple Hydrogen Bonding Ability

 

作者: Xingling Xu,   Michael Hynes,   StuartL. James,   D. Michael,   P. Mingos,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 15-27

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038239

 

出版商: Taylor & Francis Group

 

关键词: Hydrogen bond;metal;NMR;association constant

 

数据来源: Taylor

 

摘要:

The metal substituent effect on complementary triple hydrogen bonding pairs was investigated by1H NMR spectroscopy. The results demonstrated that the metal ion reduced the hydrogen bonding ability of the ADA complex [NBu4][Rh(cod)(orotate)] with 2,6-diaminopyridine.

 

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