Generation of Organometallic Crystal Architectures
作者:
Dario Braga,
Fabrizia Grepioni,
期刊:
Comments on Inorganic Chemistry
(Taylor Available online 1997)
卷期:
Volume 19,
issue 3
页码: 185-207
ISSN:0260-3594
年代: 1997
DOI:10.1080/02603599708032735
出版商: Taylor & Francis Group
关键词: crystal engineering;intermolecular interactions;organometallic molecules and crystals
数据来源: Taylor
摘要:
Organometallic crystal architectures have been examined in terms of extramolecular interactions between molecules and ions. Attention has been focused on the modelling of van der Waals crystals by means of empirical atom—atom pairwise potential energy calculations and on the possibility of generating theoretical crystal structures to be compared with those experimentally determined. Examples of crystal generation techniques for simple binary carbonyls have been reviewed. It has also been shown that organometallic crystal enginnering takes advantage of both the great structural flexibility of organometallic molecules as well as of the possibility of linking ligands via hydrogen bonds. The importance of charge assisted. C—H—-O hydrogen bonds in the construction of supramolecular aggregates is stressed.
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