Beryllium Oxide Whiskers and Platelets
作者:
P. L. Edwards,
R. J. Happel,
期刊:
Journal of Applied Physics
(AIP Available online 1962)
卷期:
Volume 33,
issue 3
页码: 943-948
ISSN:0021-8979
年代: 1962
DOI:10.1063/1.1777195
出版商: AIP
数据来源: AIP
摘要:
Beryllium oxide platelets and whiskers have been grown by heating beryllium metal in a silica furnace tube and boat with a hydrogen atmosphere for 16 hr at 1500°C. Three distinct types of whiskers formed: one type was parallel to the crystallographiccaxis, another in the basal plane ([1¯010] direction), and the third in an intermediate direction (approximately the [3¯032] direction). The first type are called ``flagpole'' whiskers because they are topped by small balls of metallic appearance; they grew at the site of the original metal charge. These whiskers have pores along their axes, except in rare instances in which, instead of a pore, a whisker may have disconnected voids along its axis. Their axial growth rate was not observed directly, but was at least 0.02 &mgr;/sec. The other two types have the more normal whisker appearance and grew at a distance of from 2 mm to 2 cm from the original metal charge. They have no pores or voids. Their growth rate was at least 0.2 &mgr;/sec. The larger platelets, which grew in the vicinity of the normal whiskers, were long in [1¯010] direction and wide in the [0001] direction. Some of the very smallest platelets grew in the basal plane. A mechanism of growth for the flagpole whiskers is proposed. It is assumed that molten beryllium balls are splashed onto a BeO substrate, and then react with water vapor to form whiskers which push the balls away from the substrate. The normal whiskers and platelets grew at a distance from the beryllium metal, and therefore their growth involves a vapor transport mechanism.
点击下载:
PDF
(464KB)
返 回