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Synthesis and Characterization of Antimony (V)-Polycobalticinium Esters

 

作者: CharlesE. Carraher,   Walter Venable,   HowardS. Blaxall,   JohnE. Sheats,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1980)
卷期: Volume 14, issue 4  

页码: 571-579

 

ISSN:0022-233X

 

年代: 1980

 

DOI:10.1080/00222338008081036

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Antimony (V) polycobalticinium esters, where the anion was PF6−, Cl−, Br−and NO3−, were synthesized. A number of factors were found to be important in the synthesis, including anion exchange and pH. The products containing PF6−are oligomeric (DPw= 7) whereas the other products are di-and trimeric. The products undergo oxidative degradation beginning about 100 to 225°C. They are near semiconductors with resistivities about 105to 107ohm-cm.

 

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