Synthesis and Characterization of Antimony (V)-Polycobalticinium Esters
作者:
CharlesE. Carraher,
Walter Venable,
HowardS. Blaxall,
JohnE. Sheats,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1980)
卷期:
Volume 14,
issue 4
页码: 571-579
ISSN:0022-233X
年代: 1980
DOI:10.1080/00222338008081036
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Antimony (V) polycobalticinium esters, where the anion was PF6−, Cl−, Br−and NO3−, were synthesized. A number of factors were found to be important in the synthesis, including anion exchange and pH. The products containing PF6−are oligomeric (DPw= 7) whereas the other products are di-and trimeric. The products undergo oxidative degradation beginning about 100 to 225°C. They are near semiconductors with resistivities about 105to 107ohm-cm.
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