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Synthese von (‐)‐(R)‐4‐Hydroxy‐β‐ionon und (‐)‐(5R, 6S)‐5‐Hydroxy‐4,5‐dihydro‐α‐ionon aus (‐)‐(S)‐α‐Ionon

 

作者: Andreas Haag,   Walter Eschenmoser,   Conrad Hans Eugster,  

 

期刊: Helvetica Chimica Acta  (WILEY Available online 1980)
卷期: Volume 63, issue 1  

页码: 10-15

 

ISSN:0018-019X

 

年代: 1980

 

DOI:10.1002/hlca.19800630103

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Synthesis of (‐)‐(R)‐4‐Hydroxy‐β‐ionone and (‐)‐(5R, 6S)‐5‐Hydroxy‐4,5‐dihydro‐α‐ionone aus (‐)‐(S)‐α‐IononeThe absolute configuration of the chiral 4‐hydroxy‐β‐ionones and 5‐hydroxy‐4,5‐dihydro‐α‐ionones has been determined by chemical connection with (‐)‐(S)‐α‐iononei.e.by stereoselective epoxidation of the latter, followed by base cat

 

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