Synthese von (‐)‐(R)‐4‐Hydroxy‐β‐ionon und (‐)‐(5R, 6S)‐5‐Hydroxy‐4,5‐dihydro‐α‐ionon aus (‐)‐(S)‐α‐Ionon
作者:
Andreas Haag,
Walter Eschenmoser,
Conrad Hans Eugster,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1980)
卷期:
Volume 63,
issue 1
页码: 10-15
ISSN:0018-019X
年代: 1980
DOI:10.1002/hlca.19800630103
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Synthesis of (‐)‐(R)‐4‐Hydroxy‐β‐ionone and (‐)‐(5R, 6S)‐5‐Hydroxy‐4,5‐dihydro‐α‐ionone aus (‐)‐(S)‐α‐IononeThe absolute configuration of the chiral 4‐hydroxy‐β‐ionones and 5‐hydroxy‐4,5‐dihydro‐α‐ionones has been determined by chemical connection with (‐)‐(S)‐α‐iononei.e.by stereoselective epoxidation of the latter, followed by base cat
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