Photoinitation of cationic polymerization. II. Laser flash photolysis of diphenyliodonium salts
作者:
S. Peter Pappas,
Betty C. Pappas,
Leslie R. Gatechair,
Wolfram Schnabel,
期刊:
Journal of Polymer Science: Polymer Chemistry Edition
(WILEY Available online 1984)
卷期:
Volume 22,
issue 1
页码: 69-76
ISSN:0360-6376
年代: 1984
DOI:10.1002/pol.1984.170220107
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractLaser flash photolysis of diphenyliodonium salts produces phenyliodinium radical cation (PhI+·), which was also generated independently by flash‐induced electron transfer from iodobenzene to a phenanthrolinium salt. Apparent second‐order rate constants were determined for reaction of the transient (PhI+·) with nucleophiles, including iodobenzene and cyclohexene oxide. Quantum yields of formation of acid from stationary photolysis of diphenyliodonium hexafluoroarsenate were found to be significantly higher than yields of iodobenzene. These results may be explained by facile reaction of PhI+·with PhI to yield a new iodonium salt together with a proton. High reactivity of PhI+·with cyclohexene oxide suggests that the transient may directly initiate cationic polymerization of e
点击下载:
PDF
(392KB)
返 回