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Elastoviscous Properties of Amorphous Polymers in the Transition Region. II. Stress‐Relaxation of Butadiene‐Styrene Copolymers

 

作者: E. Catsiff,   A. V. Tobolsky,  

 

期刊: Journal of Applied Physics  (AIP Available online 1954)
卷期: Volume 25, issue 9  

页码: 1092-1097

 

ISSN:0021-8979

 

年代: 1954

 

DOI:10.1063/1.1721820

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Experimental data have been obtained on the stress‐relaxation modulusEr(t) of several copolymers in their transition regions. The new data are expressed as master curves which can be fitted to the Gauss Error Integral form of reduced equation, as previously proposed. It appears possible to characterize the time and temperature‐dependence ofErof amorphous polymers in general by means of the parameters of this equation:E1(glassy‐state modulus),E2(rubbery‐state modulus),Td(distinctive temperature, related to second‐order transition temperature),Kd(characteristic relaxation time atTd), andh(parameter related to steepness of master curve). In the butadiene‐styrene series, the effect of composition on these parameters has been determined.

 

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