Elastoviscous Properties of Amorphous Polymers in the Transition Region. II. Stress‐Relaxation of Butadiene‐Styrene Copolymers
作者:
E. Catsiff,
A. V. Tobolsky,
期刊:
Journal of Applied Physics
(AIP Available online 1954)
卷期:
Volume 25,
issue 9
页码: 1092-1097
ISSN:0021-8979
年代: 1954
DOI:10.1063/1.1721820
出版商: AIP
数据来源: AIP
摘要:
Experimental data have been obtained on the stress‐relaxation modulusEr(t) of several copolymers in their transition regions. The new data are expressed as master curves which can be fitted to the Gauss Error Integral form of reduced equation, as previously proposed. It appears possible to characterize the time and temperature‐dependence ofErof amorphous polymers in general by means of the parameters of this equation:E1(glassy‐state modulus),E2(rubbery‐state modulus),Td(distinctive temperature, related to second‐order transition temperature),Kd(characteristic relaxation time atTd), andh(parameter related to steepness of master curve). In the butadiene‐styrene series, the effect of composition on these parameters has been determined.
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