Phase-Selective Fundamental and Second Harmonic Tensammetry
作者:
A.Karim Shallal,
HenryH. Bauer,
期刊:
Analytical Letters
(Taylor Available online 1971)
卷期:
Volume 4,
issue 4
页码: 205-217
ISSN:0003-2719
年代: 1971
DOI:10.1080/00032717108058602
出版商: Taylor & Francis Group
关键词: Adsorption;tensammetry;specific adsorption;pentanol;cyclohexanol;phase-selective;second-harmonic.
数据来源: Taylor
摘要:
Phase-selective fundamental and second-harmonic tensammetry show that the desorption of uncharged surfactants is strongly influenced by the supporting electrolyte in the region of the desorption peaks. Quantitative data, however, can be extracted only if assumptions are made about adsorption isotherms, and in particular about the potential-dependence of the surface coverage around the desorption peaks. A satisfactory model and theoretical treatment has to be developed. In the meantime, such studies can provide useful empirical data.
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