High-resolution FTIR spectroscopy of the Coriolis interacting nu3and nu9fundamentals of methylene fluoride-d2
作者:
K. L. Goh,
T. L. Tan,
P. P. Ong,
K. H. Chaw,
H. H. Teo,
期刊:
Molecular Physics
(Taylor Available online 2000)
卷期:
Volume 98,
issue 17
页码: 1343-1346
ISSN:0026-8976
年代: 2000
DOI:10.1080/002689700413596
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The Fourier transform infrared spectrum of theυ3andυ9bands of methylene fluoride-d2(CD2F2) has been recorded with an unapodized resolution of 0.0024cm-1in the frequency range 970-1080cm-1. These two bands with band centres approximately 26 cm-1apart were mutually coupled by Coriolis interactions. By fitting a total of 1639 infrared transitions of bothυ3andυ9with a standard deviation of 0.00084cm-1S/S using a Watson'sA-reduced Hamiltonian in theIrrepresentation with the inclusion of a first orderc-type Coriolis resonance term, two sets of rovibrational constants forυ3= 1 andυ9= 1 states were derived. Theυ3band isB-type while theυ9 band isA-type with band centres at 1030.1573 ± 0.0003 and 1003.7435 ± 0.0001cm-1, respectively.
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