首页   按字顺浏览 期刊浏览 卷期浏览 High-resolution FTIR spectroscopy of the Coriolis interacting nu3and nu9fundamentals of...
High-resolution FTIR spectroscopy of the Coriolis interacting nu3and nu9fundamentals of methylene fluoride-d2

 

作者: K. L. Goh,   T. L. Tan,   P. P. Ong,   K. H. Chaw,   H. H. Teo,  

 

期刊: Molecular Physics  (Taylor Available online 2000)
卷期: Volume 98, issue 17  

页码: 1343-1346

 

ISSN:0026-8976

 

年代: 2000

 

DOI:10.1080/002689700413596

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The Fourier transform infrared spectrum of theυ3andυ9bands of methylene fluoride-d2(CD2F2) has been recorded with an unapodized resolution of 0.0024cm-1in the frequency range 970-1080cm-1. These two bands with band centres approximately 26 cm-1apart were mutually coupled by Coriolis interactions. By fitting a total of 1639 infrared transitions of bothυ3andυ9with a standard deviation of 0.00084cm-1S/S using a Watson'sA-reduced Hamiltonian in theIrrepresentation with the inclusion of a first orderc-type Coriolis resonance term, two sets of rovibrational constants forυ3= 1 andυ9= 1 states were derived. Theυ3band isB-type while theυ9 band isA-type with band centres at 1030.1573 ± 0.0003 and 1003.7435 ± 0.0001cm-1, respectively.

 

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