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A Novel Donor Acceptor Substituted Chiroptical Molecular Switch: Physical Properties and Photoisomerization Behavior

 

作者: R.A. Van Delden,   A.M. Schoevaars,   B.L. Feringa,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 344, issue 1  

页码: 1-6

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023807

 

出版商: Taylor & Francis Group

 

关键词: Molecular Switches;Chirality;Photochromism

 

数据来源: Taylor

 

摘要:

A novel donor acceptor substituted sterically overcrowded alkene was synthesized and characterized. Photoisomerization experiments it showed that this system could be converted with high efficiency towards acisphotostationary state and although the reverse isomerization towards thetransstate was not as efficient this compound can function as a chiroptical molecular switch.

 

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