Volume Change in the Polymerization of Spirocyclic Monomers: Causes, Effects, and Applications
作者:
RobertF. Brady,
期刊:
Journal of Macromolecular Science, Part C
(Taylor Available online 1992)
卷期:
Volume 32,
issue 2
页码: 135-181
ISSN:1532-1797
年代: 1992
DOI:10.1080/15321799208021424
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Addition polymerization at constant temperature normally proceeds with reduction in the volume of the reactants. Polymerization shrinkage frequently diminishes the performance and durability of polymeric materials. In adhesives, coatings, and encapsulating materials, voids are created which serve as channels for the penetration of foreign substances and destructive agents. Matrix polymers in composite materials or surface coatings retract from reinforcing fibers and fillers, thereby reducing the bond area between them. In bulk polymers, shrinkage produces voids which reduce the strength and useful life of the end product, and molded products do not conform to molds or dies.
点击下载:
PDF (1806KB)
返 回