Crystallization kinetics for quenched Bi‐Ca‐Sr‐Cu‐O glasses
作者:
M. Tatsumisago,
C. A. Angell,
Y. Akamatsu,
S. Tsuboi,
N. Tohge,
T. Minami,
期刊:
Applied Physics Letters
(AIP Available online 1989)
卷期:
Volume 55,
issue 6
页码: 600-602
ISSN:0003-6951
年代: 1989
DOI:10.1063/1.101844
出版商: AIP
数据来源: AIP
摘要:
The kinetics of crystallization in the BixCaSrCu2Ow(x=1.5, 2.7) glasses prepared by twin‐roller and metal‐plate quenching methods have been studied by a nonisothermal method using differential scanning calorimetry. Scanning electron microscopy studies suggest surface crystallization as the dominant mechanism. The activation energy for crystal growth calculated from modified Kissinger plots assuming surface nucleation decreased with an increase in the Bi content. Such a composition dependence is consistent with that of the activation energy for viscous flow in the glass transformation range.
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