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Radiolysis of aqueous solutions of nucleic acid fragments. Reactions of pyrimidyl radicals with alcohol

 

作者: N.S. Fel,   L.A. Zaozerskaya,   P.I. Dolin,  

 

期刊: Radiation Effects  （Taylor Available online 1972）
卷期: Volume 15, issue 1-2  

页码: 57-59

 

ISSN:0033-7579

 

年代: 1972

 

DOI:10.1080/00337577208232581

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Using a steady state concentration method we have measured the rate constants of reactions of radicals, formed upon addition of OH and eaqto pyrimidine base thymine (T)—(T+OH)=R1and (T+e−aq)=R2with methanol. We find K=(0.8±0.2).104M−1sec−1and K > 2,3.103M−1sec−1respectively.

 

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