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Polymerization of acrylamide in nonionic microemulsions: Characterization of the microlatices and polymers formed

 

作者: C.Holtzscherer,   J.-P.Durand,   F.Candau,  

 

期刊: Colloid and Polymer Science  (Springer Available online 2005)
卷期: Volume 265, issue 12  

页码: 1067-1074

 

ISSN:0303-402X

 

年代: 2005

 

DOI:10.1007/BF01417464

 

出版商: Springer-Verlag-Berlin-Heidelberg

 

数据来源: Springer

 

摘要:

Free radical polymerization of acrylamide was carried out in nonionic microemulsions of water, an isoparaffinic oil, Isopar M and a blend of nonionic emulsifiers: a sorbitan sesquioleate and a polyoxyethylene sorbitol hexaoleate (HLB of the mixture: 9.3). The size and the stability of the latex particles formed after polymerization were studied as a function of monomer, emulsifier and electrolyte concentration. High emulsifier and high monomer contents favor obtaining high molecular weight polyacrylamides. It is shown that both the number of polymer chains contained in each latex particle and the size of the particles are essentially controlled by the acrylamide/emulsifier weight ratio.

 

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