首页   按字顺浏览 期刊浏览 卷期浏览 High Oxygen-Binding Affinity of Poly(4-Vinylimidazole-co-octylmethacrylate)-Cobaltporph...
High Oxygen-Binding Affinity of Poly(4-Vinylimidazole-co-octylmethacrylate)-Cobaltporphyrin Complex: Effect of Hydrogen-Bond at the Imidazole Residue

 

作者: Hiroyuki Nishide,   Aiko Kato,   Eishun Tsuchida,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 249-254

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038273

 

出版商: Taylor & Francis Group

 

关键词: cobaltporphyrin;polymer complex;oxygen binding;polymer ligand

 

数据来源: Taylor

 

摘要:

The oxygen-binding affinity of the cobalt-picketfence-porphyrin (CoP) ligated with imidazole was enhanced in the presence of an additive which forms a hydrogen-bond with the ligated imidazole. The CoP complex with poly(4(5)-vinylimidazole-co-octylmethacrylate) rapidly and reversibly bound oxygen and showed very high oxygen-binding affinity: The oxygen transport in the CoP-polymer membrane was efficiently facilitated.

 

点击下载:  PDF (278KB)



返 回