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Statistical mechanical theory for discotic liquid crystals Discotic nematic-isotropic transition properties

 

作者: K. Singh,   U.P. Singh,   S. Singh,  

 

期刊: Liquid Crystals  (Taylor Available online 1988)
卷期: Volume 3, issue 5  

页码: 617-629

 

ISSN:0267-8292

 

年代: 1988

 

DOI:10.1080/02678298808086406

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A statistical mechanical theory is applied to study the equilibrium properties of discotic nematic liquid crystals. We report the calculation of thermodynamic properties for a model system composed of molecules interacting through angle-dependent pair potentials which can be broken up into rapidly varying short-ranged repulsions and weak long-range attractions. The repulsive interaction is represented by a repulsion between hard oblate ellipsoids of revolution and is a short-range, rapidly-varying, potential. The influence of attractive potentials, represented by dispersion and quadrupole interactions on a variety of thermodynamic properties is analysed. It is found that the thermodynamic properties for the discotic nematic-isotropic transition are highly sensitive to the form of effective one-body orientational perturbation potential. The discontinuity in the transition properties is more pronounced in the case of quadrupole interaction than for anisotropic dispersion interaction. A remarkable symmetry in the transition properties between prolate ellipsoids (ordinary nematic) and oblate ellipsoids (discotic nematic) is observed.

 

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