Chlorinated alcohols: IV. The chlorination of oleic acid
作者:
J.E.Menting,
R.A.Grimm,
J.K.Weil,
A.J.Stirton,
期刊:
Journal of the American Oil Chemists’ Society
(Springer Available online 2006)
卷期:
Volume 46,
issue 2
页码: 85-87
ISSN:0003-021X
年代: 2006
DOI:10.1007/BF02541214
出版商: Springer-Verlag-Berlin-Heidelberg
数据来源: Springer
摘要:
Chlorination of oleic acid gave mainly 9,10-dichlorosteraic acid but other products were also formed. By-products included the dimer, 9(10)-(9,10-dichlorostearolyoxy)-10(9)-chlorostearic acid, and the related trimer, formed independent of temperature in the range examined (−20 to +29 C). Higher solvent-oleic acid ratios decreased the amounts of dimer and trimer; chlorination in the presence of hydrogen chloride did not. The equivalent weight of 9,10-dichlorostearic acid was found to increase markedly upon treatment with chlorine and light, but in the dark the acid was apparently unchanged. These effects were independent of temperatur
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