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Chlorinated alcohols: IV. The chlorination of oleic acid

 

作者: J.E.Menting,   R.A.Grimm,   J.K.Weil,   A.J.Stirton,  

 

期刊: Journal of the American Oil Chemists’ Society  (Springer Available online 2006)
卷期: Volume 46, issue 2  

页码: 85-87

 

ISSN:0003-021X

 

年代: 2006

 

DOI:10.1007/BF02541214

 

出版商: Springer-Verlag-Berlin-Heidelberg

 

数据来源: Springer

 

摘要:

Chlorination of oleic acid gave mainly 9,10-dichlorosteraic acid but other products were also formed. By-products included the dimer, 9(10)-(9,10-dichlorostearolyoxy)-10(9)-chlorostearic acid, and the related trimer, formed independent of temperature in the range examined (−20 to +29 C). Higher solvent-oleic acid ratios decreased the amounts of dimer and trimer; chlorination in the presence of hydrogen chloride did not. The equivalent weight of 9,10-dichlorostearic acid was found to increase markedly upon treatment with chlorine and light, but in the dark the acid was apparently unchanged. These effects were independent of temperatur

 

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