Individual point defect formation parameters for AgBr, AgCl, and NaCl
作者:
S.K. Wonnell,
L.M. Slifkin,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1991)
卷期:
Volume 119-121,
issue 1
页码: 135-140
ISSN:1042-0150
年代: 1991
DOI:10.1080/10420159108224867
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
We discuss the derivation of the formation enthalpy and entropy of the individual native defect components of AgBr, AgCl, and NaCl, from measurements of the subsurface ionic space charge potential. The straighforward intrinsic analysis for AgBr yields a silver vacancy formation energy of (0.30±0.04)eV + (7.2 ± 2.0)kT. The NaCl analysis involves some assumptions about impurity concentrations and association, and yields a cation vacancy formation free energy of (1.24 ± 0.12) − (6.53 ± 1.4) kT. For NaCl, the formation energy is divided almost equally between the two vacancies; in AgBr and AgCl the silver interstitial formation free energy vanishes when extrapolated to the melting point.
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