Dielectric Loss due to Impurity Cation Migration in &agr; Quartz
作者:
E. H. Snow,
P. Gibbs,
期刊:
Journal of Applied Physics
(AIP Available online 1964)
卷期:
Volume 35,
issue 8
页码: 2368-2374
ISSN:0021-8979
年代: 1964
DOI:10.1063/1.1702865
出版商: AIP
数据来源: AIP
摘要:
The dielectric constant and loss factor of natural quartz single crystals have been measured in the temperature range from room temperature to 573°C, and in the frequency range from 50 cps to 100 kc/sec. Parallel to thecaxis a large dispersion in the dielectric constant of the order of &egr;s‐&egr;∞= 500 was observed. Associated with this dispersion is a peak in the loss factor of the order of &egr;″max= 250. The data were analyzed in terms of the Debye equations with a single thermally activated relaxation time. The activation energy is about 16.7 kcal/mole. Perpendicular to thecaxis no peak in &egr;″ was observed, but both &egr;′ and &egr;″ begin to increase at low frequencies and high temperatures.The loss peak parallel to thecaxis was substantially reduced when impurities were removed by electrolysis. The introduction of Ag, Cu, or Na gave rise to new peaks while Li tended to reproduce the original peak. It is concluded that the original loss was due to the motion of Li+ions along structural channels parallel to thecaxis. From the charge transported in electrolysis experiments, it can be inferred that the number of ions involved was about 5×1017per cm3. The observed activation energy is believed to be the Coulomb binding energy between a substitutional Al3+ion and an interstitial Li+ion.
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