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thermotropic Liquid-Crystalline Polyesters Containing Cyclooctyl Units III. Effect of Mesogen Length and the Dual Role of the Cyclooctyl Ring

 

作者: J.M. G. Cowie,   H.H. Wu,  

 

期刊: Liquid Crystals  (Taylor Available online 1988)
卷期: Volume 3, issue 10  

页码: 1387-1391

 

ISSN:0267-8292

 

年代: 1988

 

DOI:10.1080/02678298808086618

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Three polyesters have been prepared which incorporate the cyclooctyl unit in the main chain. The number of phenyl rings in the repeat unit was varied from one to three and in each case the polymer exhibited a liquid-crystalline phase. It has been shown that the cyclooctyl ring may act both as a semi-flexible spacer as well as an integral part of the mesogenic unit. This dual role is of considerable interest and has not been reported previously.

 

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