Steady‐state methanation kinetics over a Ni/Al2O3catalyst
作者:
Rajiv Yadav,
R. G. Rinker,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1993)
卷期:
Volume 71,
issue 2
页码: 202-208
ISSN:0008-4034
年代: 1993
DOI:10.1002/cjce.5450710206
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: methanation kinetics;methanation rate law;carbon monoxide methanation;methanation catalyst
数据来源: WILEY
摘要:
AbstractExtensive kinetic data for the methanation reaction over a Ni/Al2O3catalyst were obtained in a specially designed gradientless reactor operating at steady state. The reactor pressure was 101.3 kPa, and three temperatures were used, namely, 503, 513 and 523 K. The following three‐parameter phenomenological model based on a proposed Langmuir‐Hinshelwood mechanism adequately describes the data:r= L2K3K40.5k5P0.5H2Pco/ [1 +K3(k5/k6)Pco +K40.5P0.5H2]2With dissociative adsorption of hydrogen and hydrogen‐assisted dissociation of adsorbed carbon monoxide, the postulated mari is the CH surface group, and the rds is the hydrogenation of the surface CH
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