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Linewidth uniformity versus etch rate uniformity in refractory metal plasma etching

 

作者: Sami Franssila,  

 

期刊: Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena  (AIP Available online 1994)
卷期: Volume 12, issue 5  

页码: 2963-2969

 

ISSN:1071-1023

 

年代: 1994

 

DOI:10.1116/1.587543

 

出版商: American Vacuum Society

 

关键词: TUNGSTEN;MOLYBDENUM;NIOBIUM;ETCHING;PLASMA SOURCES;IMPURITIES;SPUTTERING;W;Mo;Nb

 

数据来源: AIP

 

摘要:

Etch rate, etch rate uniformity, linewidth uniformity, and microloading in tungsten, molybdenum, and niobium plasma etching have been studied. Electrical linewidth data with typically 100–300 measured lines/wafer have been used. Relation between linewidth uniformity and etched depth uniformity (as measured by profilometer) has been explored. Effects of tungsten film deposition processes (oxygen contamination) have been studied. Tungsten etch rate maximum in SF6/O2is at 85/15 ratio for the oxygen contaminated films, but higher oxygen percentage in SF6/O2is required for maximum etch rate of pure films. Oxygen impurities in the tungsten film affect the etch rate but neither linewidth nor linewidth uniformity. In molybdenum etching in Cl2/O2plasma the etched depth uniformity gives an overly pessimistic uniformity value even though linewidth uniformity is acceptable 12% (3σ). Addition of 3%–6% of CHF3to Cl2/O2is shown to change microloading characteristics and to improve linewidth uniformity. On 100 mm wafers, 6%–12% (3σ) linewidth uniformities were obtained for the different metals. Linewidth differences between isolated and array lines were 4%–8%.

 

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