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Binary vapor‐liquid equilibrium data thermodynamic consistency tests

 

作者: C.‐Y. Lu Benjamin,   C. K. Ho James,   I. H. Spinner,  

 

期刊: The Canadian Journal of Chemical Engineering  （WILEY Available online 1962）
卷期: Volume 40, issue 1  

页码: 16-24

 

ISSN:0008-4034

 

年代: 1962

 

DOI:10.1002/cjce.5450400106

 

出版商: Wiley Subscription Services, Inc., A Wiley Company

 

数据来源: WILEY

 

摘要:

AbstractVisual methods for testing thermodynamic consistency of binary vapor‐liquid equilibrium data by means of the Gibbs‐Duhem equation on a log γ vs. x plot at strategic liquid compositions are reviewed. The justifications for these methods and guidance for their applications are presented. Furthermore, these methods have been extended to test the thermodynamic consistency of equilibrium data (t‐P‐x‐y

 

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