Behavior of Ni in carbon nanotube nucleation
作者:
Masako Yudasaka,
Rie Kikuchi,
Yoshimasa Ohki,
Etsuro Ota,
Susumu Yoshimura,
期刊:
Applied Physics Letters
(AIP Available online 1997)
卷期:
Volume 70,
issue 14
页码: 1817-1818
ISSN:0003-6951
年代: 1997
DOI:10.1063/1.118700
出版商: AIP
数据来源: AIP
摘要:
A nucleation model was proposed for a carbon nanotube enclosing a Ni bar which was grown by chemical vapor deposition (CVD) at 700 °C using round Ni particles. At an early stage of CVD, each round Ni particle with a diameter of about 30 nm is covered with graphite layers. The graphite-covered Ni particle is considered to be unstable because the graphite layers have a large curvature. This instability is thought to make the graphite-covered Ni particles transform into a Ni bar enclosed within a carbon nanotube. In order to verify this nucleation model, we show that the size of the round Ni particle is a decisive condition for carbon nanotube formation by CVD, and that an intermediate state of the transformation of the graphite-covered Ni particles to the carbon-nanotube-enclosed Ni bar was observed by transmission electron microscopy. ©1997 American Institute of Physics.
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